I agree with Uhmanduh and Airika that the archaeological evidence from tree rings etc
could be the result of a natural disaster such as a volcanic eruption and that the subsequent effect on agriculture and climate could have hastened the demise of empires such as the Romans/Hittites/Akkadians (other factors - such as the invasions by 'barbarians' was also an undoubted factor).
However it is possible that the tree ring/ice core evidence could be the result of a more mundane cause such as the regular solar maximum/minimum (or even a combination of eruption plus this). I haven't tried to cross-reference the dates in question as I'm too lazy.